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Ψ ψ, ψεῖ (q. v.), τό, indecl., twenty-third letter of the Ionic alphabet, Pl.Cra.427a, Callias ap.Ath.10.453d: not used in the Attic alphabet: in the Western Gr. alphabets it represents the sound χ (
A.kh): with the value ps it is found in SIG1 (Nubia, vi B. C.), etc.: as a numberal, ψ́ = 700, but ψ᾽ = 700,000.
Henry George Liddell. Robert Scott. A Greek-English Lexicon. revised and augmented throughout by. Sir Henry Stuart Jones. with the assistance of. Roderick McKenzie. Oxford. Clarendon Press. 1940.

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